Scientific production


Journal articles


1997


119. R. Poli*: “Molybdenum Open Shell Organometallics. Spin State Changes and Pairing Energy Effects”, Acc. Chem. Res. 1997, 30, 494-501.


118. I. Cacelli, D. W. Keogh, R. Poli, A. Rizzo*: “Theoretical studies of the 15- and 17-electron Structures of Cyclopentadienylchromium(III) and cyclopentadienylmolybdenum(III) compounds. Dichloride and Dimethyl Compounds”, J. Phys. Chem. A 1997, 101, 9801-9812.


117. D. W. Keogh, R. Poli*: “Experimental and Theoretical Comparison Between CpMCl3Ln Systems of NbIV and MoIV”, J. Chem. Soc., Dalton Trans. 1997, 3325-3333 (special volume on occasion of the 1st anniversary of the death of Sir Geoffrey Wilkinson).


116. J. C. Fettinger, D. W. Keogh, B. Pleune, R. Poli*: “Structure of the 17-Electron Cp*MoCl2(dppe): An Unexpectedly Trans Geometry in the Solid State”, Inorg. Chim. Acta 1997, 26, 1-5.


115. R. Galassi, R. Poli*, E. A. Quadrelli, J. C. Fettinger: “H+/AuPPh3+ Exchange for the Hydride Complexes CpMoH(CO)2(L) (L = PMe3, PPh3, CO). Formation and Structure of [Cp(CO)2(PMe3)Mo(AuPPh3)2]+[BF4]-”, Inorg. Chem. 1997, 36, 3001-3007.


114. S. P. Mattamana, R. Poli*: “Accessibility of 17-Electron Structures for Cyclopentadienylchromium(III) Compounds. 2. Cyanide Derivatives with 15- and 17-Electron Configurations”, Organometallics 1997, 16, 2427-2433.


113. L.-S. Wang, J. C. Fettinger*, R. Poli: “Cyclopentadienylmolybdenum(II) and -(III) Complexes Containing Diene and Allyl Ligands. 1. Isomeric Preferences and Isomerization Rates in a Pair of Redox-Related Organometallic Complexes”, J. Am. Chem. Soc. 1997, 119, 4453-4464.


112. J. C. Fettinger, H.-B. Kraatz, R. Poli*, E. A. Quadrelli: “First Mononuclear Paramagnetic Organometallics of MoII and MoIII Containing Terminal Hydroxide Ligands. X-ray structure of [Mo(η5-C5H5)(OH)(PMe3)3]BF4”, J. Chem. Soc., Chem. Commun. 1997, 889-890.


111. B.Pleune, R. Poli*, J. C. Fettinger: “Synthesis, Structure, and Protonation Studies of Cp*MH3(dppe) (M = Mo, W). Pseudo-Trigonal Prismatic vs. Pseudo-Octahedral Structures for Half-sandwich Group 6 M(IV) Derivatives”, Organometallics 1997, 16, 1581-1594.


110. F. Abugideiri, J. C. Fettinger, B. A. Pleune, R. Poli*, C. A. Bayse, M. B. Hall*: “Synthesis, Structure, and Hydride-Deuteride Exchange Studies on CpMoH3(PMe2Ph)2, and Theoretical MP2 Studies of the CpMoH3(PH3)2 Model System”, Organometallics 1997, 16, 1179-1185.


109. D. W. Keogh, R. Poli*: “Spin State Change in Organometallic Reactions. Experimental and MP2 Theoretical Studies of the Thermodynamic and Kinetics of the CO and N2 Addition to Spin Triplet Cp*MoCl(PMe3)2”, J. Am. Chem. Soc. 1997, 119, 2516-2523.


108. I. Cacelli, D. W. Keogh, R. Poli*, A. Rizzo: “Electron Pairing as a Stabilizing Factor in Open-Shell Organometallics. The Case of 15-Electron CpMCl2(PH3) (M = Cr and Mo)”, New J. Chem. 1997, 21, 133-135.


107. A. A. Saleh, B. A. Pleune, J. C. Fettinger, R. Poli*: “Hydrotris(pyrazolyl)borate Molybdenum Chemistry: Spin Triplet Sixteen-electron Carbonyl Derivatives of Molybdenum(II), and the X-ray Structure of the Oxo Compound {HB(3,5-Me2C3N2H)3}MoOI2”, Polyhedron 1997, 16, 1391-1397.